Gas Laws - Key terms



ABSOLUTE TEMPERATURE:

Temperature in relation to absolute zero (−273.15°C or −459.67°F). Its unit is the Kelvin (K), named after William Thomson, Lord Kelvin (1824-1907), who created the scale. The Kelvin and Celsius scales are directly related; hence, Celsius temperatures can be converted to Kelvins (for which neither the word or symbol for "degree" are used) by adding 273.15.

AVOGADRO'S LAW:

A statement, derived by the Italian physicist Amedeo Avogadro (1776-1856), which holds that as the volume of gas increases under isothermal and isobarometric conditions, the number of molecules (expressed in terms of mole number), increases as well. Thus the ratio of volume to mole number is aconstant.

BOYLE'S LAW:

A statement, derived by English chemist Robert Boyle (1627-1691), which holds that for gases in isothermal conditions, an inverse relationship exists between the volume and pressure of a gas. This means that the greater the pressure, the less the volume and viceversa, and therefore the product of pressure multiplied by volume yields a constantfigure.

CHARLES'S LAW:

A statement, derived by French physicist and chemist J. A. C. Charles (1746-1823), which holds that for gases in isobarometric conditions, the ratio between the volume and temperature of a gas is constant. This means that the greater the temperature, the greater the volume and vice versa.

DALTON'S LAW OF PARTIAL PRESSURE:

A statement, derived by the English chemist John Dalton (1766-1844), which holds that the total pressure of a gas is equal to the sum of its partial pressures—that is, the pressure exerted by each component of the gas mixture.

GAY-LUSSAC'S LAW:

A statement, derived by the French physicist and chemist Joseph Gay-Lussac (1778-1850), which holds that the pressure of a gas is directly related to its absolute temperature. Hence the ratio of pressure to absolute temperature is a constant.

HENRY'S LAW:

A statement, derived by the English chemist William Henry (1774-836), which holds that the amount of gas dissolved in a liquid is directly proportional to the partial pressure of the gas above the solution. This holds true only forgases, such as hydrogen and oxygen, that are capable of dissolving in water without undergoing ionization.

IDEAL GAS LAW:

A proposition, also known as the combined gas law, that draws on all the gas laws. The ideal gas law can be expressed as the formula pV = nRT, where p stands for pressure, V for volume, n for number of moles, and T for temperature. R is known as the universal gas constant, a figure equal to 0.0821 atm · liter/mole · K.

INVERSE RELATIONSHIP:

A situation involving two variables, in which one of the two increases in direct proportion to the decrease in the other.

IONIZATION:

A reaction in which anatom or group of atoms loses one or more electrons. The atoms are then converted toions, which are either wholly positive or negative in charge.

ISOTHERMAL:

Referring to a situation in which temperature is kept constant.

ISOBAROMETRIC:

Referring to a situation in which pressure is kept constant.

MOLE:

A unit equal to 6.022137 × 10 23 molecules.

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